WebSep 4, 2001 · Cryptophane-A has been shown to bind xenon with a binding constant K ≈10 3 ⋅M −1 in organic solvents ( 12 ), but the affinity is likely to increase in aqueous solution because of the hydrophobic nature of xenon. WebAug 13, 2016 · For instance, the water-soluble congener 58 of cryptophane-E (Fig. 21.17), possessing three propylenedioxy linkers and six carboxylic acid moieties binds tetramethyl ammonium salts efficiently. The molecular recognition between ammonium species and cryptophane host is strongly dependent on the molecular volume of the guest.
Cryptophane–xenon complexes for 129 Xe MRI applications
WebNov 4, 2024 · 14. The method of claim 13, wherein the stabilizer is selected from the group consisting of a polysaccharide, a cryptand, a cryptophane, a cavitand, a crown ether, a dendrimer, a nanotube, a calixarene, a valinomycin, a nigericin, and combinations thereof. 15. The method of claim 13, further comprising contacting the sample with a counterstain. 16. Webthe prototype is a cryptophane-A molecule (21) with a polar peptide chain attached to make the cryptophane water soluble. ¶To whom reprint requests should be addressed. E-mail: [email protected]. **Present address: Departments of Chemistry and Biological Sciences, National University of Singapore, 3 Science Drive, Singapore 117543. green southie shamrock shirt
Fully collapsed "imploded" cryptophanes in solution and
WebAug 18, 2009 · Supramolecular cryptophane-A was synthesized from vanillyl alcohol using a double trimerisation method and deposited on a QCM device via electrospray method. The sensor was exposed to various concentrations of CH 4 Keywords Supramolecular Cryptophane Gas senor Quartz crystal microbalance (QCM) Methane Room temperature … WebJan 1, 2015 · Cryptophane-E-(OEt)6 was synthesized and investigated the interaction with chloroform by fluorescence spectroscopy. The results indicate that cryptophane-E-(OEt)6 is able to selectively... WebIn this study we analyse from a theoretical perspective the encapsulation of both gaseous H2 and CO2 at different conditions of pressure and temperature in a Type II porous liquid, composed by nanometric scale cryptophane-111 molecules dispersed in dichloromethane, using atomistic molecular dynamics. Gaseous H2 tends to occupy cryptophane–111’s … green south gainesville